Hidrazit Esaslı Maleik Asit Metal Komplekslerinin Kolorimetrik ve Spektrofotometrik Olarak İncelenmesi
Abstract views: 39
/ 
PDF downloads: 45
Keywords:
Maleik Asit Hidrazit, Metal Kompleks, Sürekli Değişim Metodu, StokiyometriAbstract
Bu çalışmada, bir maleik asit hidrazit olan (2Z)-4-hidrazin-(4-oksobüt-2-enoik asit), maleik anhidrit
ile hidrazin monohidratın etanol içindeki reaksiyonundan elde edilmiştir. Sentezlenen bu hidrazit esaslı
ligand bileşiğinin Cu(II), Zn(II), Cd(II), Ca(II), Zn(II), Mg(II), Mn(II) ve Fe(III) metal iyonlarıyla
oluşturduğu komplekslerin kemosensör yetenekleri kolorimetrik olarak belirlenmiştir. Ligand bileşiği ile
Fe(III) metal iyonu arasındaki etkileşmenin stokiyometrisi sürekli değişim yöntemi ile hesaplanmıştır. Bu
metal kompleks bileşiğindeki, ligand:metal iyonları arasındaki stokiyometrik oran spektrofotometrik
ölçümlerle 1:1 olarak tespit edilmiştir.
Downloads
References
Yan, Z. Zhao, Q. Wen, M. Hu, L. Zhang, X. and You, J., "A novel polydentate ligand chromophore for simultaneously colorimetric detection of trace Ag+ and Fe3+", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2017, 186: 17-22
Wei, T.-B. Zhang, P. Shi, B.-B. Chen, P. Lin, Q. Liu, J. and Zhang, Y. M., "A highly selective chemosensor for colorimetric detection of Fe3+ and fluorescence turn-on response of Zn2+", Dyes and Pigments, 2013, 97: 297-302
Yong X, Su MJ, Wang W, et al. "A naked-eye chemosensor for fluoride ions: A selective easy-to-prepare test paper", Org Biomol Chem., 2013, 11(14): 2254-2257.
Wang KP, Chen JP, Zhang SJ, Lei Y, Zhong H, Chen S, Zhou XH, Hu ZQ, "Thiophene-based rhodamine as selectivef luorescence probe for Fe(III) and Al(III) in living cells", Anal Bioanal 24 Chem., 2017, 23:5547-5554
Barba-Bon A, Costero AM, Gil S, Parra M, Soto J, Martínez-Máñez R, Sancenón F., "A new selective fluorogenic probe for trivalent cations", Chem Commun., 2012, 24, 21;48
Chandra R, Manna AK, Rout K, Mondal J, Patra GK., "A dipodal molecular probe for naked eye detection of trivalent cations (Al3+, Fe3+and Cr3+) in aqueous medium and its applications in real sample analysis and molecular logic gates", RSC Adv., 2018, 8(63):35946-35958
Zhang, C. Wang, M. Zhang, Y. Li, Z. and Xu, S., "Dual colorimetric and fluorescent determination of iron(III) using a novel squaraine dye", Instrumentation Science & Technology, 2018, 46: 292-306
Berhanu AL, Gaurav, Mohiuddin I, Malik AK, Aulakh JS, Kumar V, et al. "A review of the applications of Schiff bases as optical chemical sensors", Trends in Analytical Chemistry, 2019, 116:74–91
Y. Lu, S. M. Berry and T. D. Pfister, "Engineering Novel Metalloproteins: Design of Metal-Binding Sites into Native Protein Scaffolds", Chem. Rev., 2001, 101, 3047.
Gledhill, M. ve Buck, K.N., "The organic complexation of iron in the marine environment: a review", Frontiers in microbiology, 2012, 3: 69
Henry Feuer, Emil H. White and John E. Wyman, "The Reactions of Maleic Anhydride with Hydrazine Hydrate" J. Am. Chem. Soc., 1958, 80, 14, 3790–3792
Murtadha H. Mohan, Ibtisam K. Jassim, "Synthesis, Characterization and Evaluation of the Antibacterial Activity of Some Heterocyclic Compounds", IJDDT, 2022, Vol.12 Issue 2, 734-739
