Hidrazit Esaslı Maleik Asit Metal Komplekslerinin Kolorimetrik ve Spektrofotometrik Olarak İncelenmesi
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Keywords:
Maleik Asit Hidrazit, Metal Kompleks, Sürekli Değişim Metodu, StokiyometriAbstract
Bu çalışmada, bir maleik asit hidrazit olan (2Z)-4-hidrazin-(4-oksobüt-2-enoik asit), maleik anhidrit
ile hidrazin monohidratın etanol içindeki reaksiyonundan elde edilmiştir. Sentezlenen bu hidrazit esaslı
ligand bileşiğinin Cu(II), Zn(II), Cd(II), Ca(II), Zn(II), Mg(II), Mn(II) ve Fe(III) metal iyonlarıyla
oluşturduğu komplekslerin kemosensör yetenekleri kolorimetrik olarak belirlenmiştir. Ligand bileşiği ile
Fe(III) metal iyonu arasındaki etkileşmenin stokiyometrisi sürekli değişim yöntemi ile hesaplanmıştır. Bu
metal kompleks bileşiğindeki, ligand:metal iyonları arasındaki stokiyometrik oran spektrofotometrik
ölçümlerle 1:1 olarak tespit edilmiştir.
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