Elektroliz Yöntemi ile Atık Yemek Yağından Biyodizel Üretimi: Sıcaklık Etkileri


Abstract views: 11 / PDF downloads: 14

Authors

  • M. Raşit ATELGE Siirt University

Keywords:

Biyodizel Üretimi, Elektroliz Yöntemi, Sıcaklık Etkisi, Atık Yemek Yağı, Biyoenerji

Abstract

Bu çalışma, elektroliz yöntemiyle atık yemek yağından biyodizel üretiminde sıcaklığın etkisini
araştırmıştır. Geleneksel transesterifikasyon yöntemlerine kıyasla, elektroliz yöntemi hammadde
içerisindeki yüksek serbest yağ asidi ve su içeriği sınırlamalarını ortadan kaldırarak avantajlar sunmaktadır.
Farklı sıcaklıklarda (25°C, 45°C ve 65°C) gerçekleştirilen deneyler sonucunda, 65°C'de en yüksek
biyodizel verimi (%96.3) elde edilmiştir. Literatürdeki benzer çalışmalarla da uyumlu olarak, sıcaklığın
artmasının biyodizel verimini olumlu yönde etkilediği görülmüştür. Öte yandan, reaksiyon süresinin de
optimize edilmesi gerektiği, aksi halde uzun süreli reaksiyonların istenmeyen sabunlaşma reaksiyonlarına
yol açabileceği vurgulanmıştır. Sonuç olarak, elektroliz yöntemiyle biyodizel üretiminin ekonomik ve
çevresel açıdan sürdürülebilir bir alternatif olduğu, enerji verimliliği ve çevresel etkiler bakımından önemli
katkılar sağlayabileceği ortaya konmuştur. Bu bulgular, elektroliz yöntemiyle biyodizel üretiminin daha
geniş ölçekte uygulanabilirliğini ve verimliliğini geliştirme potansiyeline işaret etmektedir.

Downloads

Download data is not yet available.

Author Biography

M. Raşit ATELGE, Siirt University

Department of Mechanical Engineering, Faculty of Engineering, Türkiye

References

A. International Energy. Statistics Report. Key World Energy Statistics 2020. Springer Berlin/Heidelberg, Germany2020.

B. Changmai, C. Vanlalveni, A.P. Ingle, R. Bhagat, L. Rokhum. Widely used catalysts in biodiesel production: A review. RSC Advances. 10 (2020) 41625-79. 10.1039/d0ra07931f.

S.Z. Naji, C.T. Tye. A review of the synthesis of activated carbon for biodiesel production: Precursor, preparation, and modification. Energy Conversion and Management: X. 13 (2022) 100152-. 10.1016/j.ecmx.2021.100152.

M. Kayfeci, A. Keçebaş, M. Bayat. Hydrogen production. Solar Hydrogen Production Processes, Systems and Technologies. Elsevier2019. pp. 45-83.

V. Rahimi, M. Shafiei. Techno-economic assessment of a biorefinery based on low-impact energy crops: A step towards commercial production of biodiesel, biogas, and heat. Energy Conversion and Management. 183 (2019) 698-707. 10.1016/j.enconman.2019.01.020.

M. Subramaniam, J.M. Solomon, V. Nadanakumar, S. Anaimuthu, R. Sathyamurthy. Experimental investigation on performance, combustion and emission characteristics of DI diesel engine using algae as a biodiesel. Energy Reports. 6 (2020) 1382-92. https://doi.org/10.1016/j.egyr.2020.05.022.

A. Pugazhendhi, A. Alagumalai, T. Mathimani, A.E. Atabani. Optimization, kinetic and thermodynamic studies on sustainable biodiesel production from waste cooking oil: An Indian perspective. Fuel. 273 (2020) 117725-. 10.1016/j.fuel.2020.117725.

A. Sander, M. Antonije Košćak, D. Kosir, N. Milosavljević, J. Parlov Vuković, L. Magić. The influence of animal fat type and purification conditions on biodiesel quality. Renewable Energy. 118 (2018) 752-60. https://doi.org/10.1016/j.renene.2017.11.068.

V. Mandari, S.K. Devarai. Biodiesel Production Using Homogeneous, Heterogeneous, and Enzyme Catalysts via Transesterification and Esterification Reactions: a Critical Review. BioEnergy Research. (2021). 10.1007/s12155-021-10333-w.

D.C. Rakopoulos, C.D. Rakopoulos, R.G. Papagiannakis, D.C. Kyritsis. Combustion heat release analysis of ethanol or n-butanol diesel fuel blends in heavy-duty di diesel engine. Fuel. 90 (2011) 1855-67. 10.1016/j.fuel.2010.12.003.

A.E. Atabani, I.A. Badruddin, T.M.I. Mahlia, H.H. Masjuki , M. Mofijur, K.T. Lee, et al. Fuel Properties of Croton megalocarpus, Calophyllum inophyllum, and Cocos nucifera (coconut) Methyl Esters and their Performance in a Multicylinder Diesel Engine. Energy Technology. 1 (2013) 685-94. https://doi.org/10.1002/ente.201300110.

D.-S. Kim, M. Hanifzadeh, A. Kumar. Trend of biodiesel feedstock and its impact on biodiesel emission characteristics. Environmental Progress & Sustainable Energy. 37 (2018) 7-19. https://doi.org/10.1002/ep.12800.

Y. Zhao, C. Wang, L. Zhang, Y. Chang, Y. Hao. Converting waste cooking oil to biodiesel in China: Environmental impacts and economic feasibility. Renewable and Sustainable Energy Reviews. 140 (2021) 110661-. 10.1016/j.rser.2020.110661.

OECD/FAO. OECD-FAO Agricultural Outlook 2021-2030. Paris, 2021.

O. Awogbemi, D.V.V. Kallon, V.S. Aigbodion. Trends in the development and utilization of agricultural wastes as heterogeneous catalyst for biodiesel production. Journal of the Energy Institute. 98 (2021) 244-58. 10.1016/j.joei.2021.06.017.

Z.-E. Tang, S. Lim, Y.-L. Pang, H.-C. Ong, K.-T. Lee. Synthesis of biomass as heterogeneous catalyst for application in biodiesel production: State of the art and fundamental review. Renewable and Sustainable Energy Reviews. 92 (2018) 235-53. https://doi.org/10.1016/j.rser.2018.04.056.

M. Narasimhan, M. Chandrasekaran, S. Govindasamy, A. Aravamudhan. Heterogeneous nanocatalysts for sustainable biodiesel production: A review. Journal of Environmental Chemical Engineering. 9 (2021) 104876. https://doi.org/10.1016/j.jece.2020.104876.

L.J. Konwar, J. Boro, D. Deka. Activated Carbon Supported CaO from Waste Shells as a Catalyst for Biodiesel Production. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 40 (2018) 601-7. 10.1080/15567036.2012.733483.

J. Cheng, H. Guo, X. Yang, Y. Mao, L. Qian, Y. Zhu, et al. Phosphotungstic acid-modified zeolite imidazolate framework (ZIF-67) as an acid-base bifunctional heterogeneous catalyst for biodiesel production from microalgal lipids. Energy Conversion and Management. 232 (2021) 113872. https://doi.org/10.1016/j.enconman.2021.113872.

M. Jayakumar, N. Karmegam, M.P. Gundupalli, K. Bizuneh Gebeyehu, B. Tessema Asfaw, S.W. Chang, et al. Heterogeneous base catalysts: Synthesis and application for biodiesel production – A review. Bioresource Technology. 331 (2021) 125054. https://doi.org/10.1016/j.biortech.2021.125054.

H.K. Ooi, X.N. Koh, H.C. Ong, H.V. Lee, M.S. Mastuli, Y.H. Taufiq-Yap, et al. Progress on modified calcium oxide derived waste-shell catalysts for biodiesel production. Catalysts. 11 (2021) 1-26. 10.3390/catal11020194.

C. Sun, Y. Hu, F. Sun, Y. Sun, G. Song, H. Chang, et al. Comparison of biodiesel production using a novel porous Zn/Al/Co complex oxide prepared from different methods: Physicochemical properties, reaction kinetic and thermodynamic studies. Renewable Energy. 181 (2022) 1419-30. 10.1016/j.renene.2021.09.122.

M. Helmi, K. Tahvildari, A. Hemmati. Parametric optimization of biodiesel synthesis from Capparis spinosa oil using NaOH/NaX as nanoheterogeneous catalyst by response surface methodology. Brazilian Journal of Chemical Engineering. 38 (2021) 61-75. 10.1007/s43153-020-00074-2.

B. Narowska, M. Kułażyński, M. Łukaszewicz, E. Burchacka. Use of activated carbons as catalyst supports for biodiesel production. Renewable Energy. 135 (2019) 176-85. 10.1016/j.renene.2018.11.006.

M.A. Yahya, Z. Al-Qodah, C.W.Z. Ngah. Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review. Renewable and Sustainable Energy Reviews. 46 (2015) 218-35. https://doi.org/10.1016/j.rser.2015.02.051.

T.V. de Medeiros, A. Macina, R. Naccache. Graphitic carbon nitrides: Efficient heterogeneous catalysts for biodiesel production. Nano Energy. 78 (2020) 105306-. 10.1016/j.nanoen.2020.105306.

Başak Burcu, U. Z. U. N., Kılıç, M., & Pütün, A. E. Ayçiçeği Yağından Transesterifikasyon Yöntemiyle Biyodizel Üretimi.

Barnval. B.K., Sharma, M.P., Prospects of Biodiesel Production from Vegetable Oils in India, Renewable and Sustainable Energy Reviews, 1-16,(2004)

Downloads

Published

2024-10-02

How to Cite

ATELGE, M. R. (2024). Elektroliz Yöntemi ile Atık Yemek Yağından Biyodizel Üretimi: Sıcaklık Etkileri . International Journal of Advanced Natural Sciences and Engineering Researches, 8(9), 126–132. Retrieved from https://as-proceeding.com/index.php/ijanser/article/view/2052

Issue

Section

Articles