Production and Characterization of Epoxy Resin-Based Biocomposites Reinforced with Citrus maxima Peel
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DOI:
https://doi.org/10.5281/zenodo.14188632Keywords:
Citrus Maxima, Biocomposite, Bulk Density, Hardness, Thermal Conductivity, Thermal StabilityAbstract
In this study, epoxy resin-based biocomposite production and characterization with the addition
of Citrus maxima (pomelo) peel is carried out. To increase the environmental sustainability of composites,
pomelo peel is dried and ground as bio-waste and mixed into epoxy resin as a reinforcement material.
During the experimental production process, optimization studies are carried out and different amounts of
pomelo peel powder (0 wt.%, 1 wt.%, 3 wt.%, 5 wt.%, and 7 wt.%) are mixed homogeneously with the
epoxy resin matrix and cast into standard molds. The mechanical, thermal, and morphological properties of
the obtained biocomposites have been examined in detail. When the results are evaluated, both the bulk
density and Shore D hardness of the biocomposite decrease with pomelo powder supplementation. When
this type of biomass is added to the resulting epoxy-based biocomposite, the thermal conductivity
coefficient also reduces. In the thermal decomposition experiments of the biocomposite, it is understood
that pomelo supplementation increases thermal stability. When scanning electron microscope (SEM)
images of the biocomposites have been investigated, it is seen that there is a good interfacial adhesion
between the epoxy matrix and the pomelo peel. However, when Fourier-transform infrared spectroscopy
(FTIR) spectra are examined, it is understood that this interaction is physical. These results show that
pomelo peel-reinforced epoxy-based biocomposites can potentially be used as environmentally friendly and
low carbon footprint biomaterials.
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References
Lü, Z.; Zhang, Z.; Wu, H.; Yu, J. (2016). Phenolic Composition and Antioxidant Capacities of Chinese Local Pummelo Cultivars’ Peel. Hortic. Plant J. 2, 133–140.
Jain, A., Ornelas-Paz, J.J., Obenland, D., Rodriguez, K., Prakash, A., (2017). Effect of phytosanitary irradiation on the quality of two varieties of pummelos (Citrus maxima (burm.) merr. Sci. Hortic. 217, 36–47.
Chaiyana, W., Phongpradist, R., & Leelapornpisid, P. (2014). Characterization of hydrodistillated pomelo peel oil and the enhancement of biological activities using microemulsion formulations. International Journal of Pharmacy and Pharmaceutical Sciences, 6(9), 596-602.
Salihah, B. N., Rosnah, S., & Norashikin, A. A. (2015). Mass modeling of Malaysian varieties Pomelo fruit (Citrus grandis L. Osbeck) with some physical characteristics. International Food Research Journal, 22(2), 488.
Tian, X., Liu, Y., Feng, X., Khaskheli, A. A., Xiang, Y., & Huang, W. (2018). The effects of alcohol fermentation on the extraction of antioxidant compounds and flavonoids of pomelo peel. LWT, 89, 763-769.
Shafiya R., Kaol R., Sofi S.A., Bashir N., Nazir F., Nayik G.A. (2018). Citrus peel as a source of functionalingredient: a review. J Saudi Soc Agric Sci. 17(4):351–358.
Buran, A. (2022). Türkiye’de Yetiştirilen Citrus maxima (Şadok) Meyvesinin Atık Kısımlarındaki Antioksidan, Fenolik ve Flavonoid Madde Miktarlarının Belirlenmesi. İstanbul Ticaret Üniversitesi Fen Bilimleri Dergisi, 21 (42), 396-408.
Ajeet Singh and Navneet. (2016). Evaluation of Antimicrobial Potential and Phytochemical Assessment of Citrus maxima Burm. Seeds Extracts Against Respiratory Tract Pathogens. N Y Sci J., 9(9):4-10.
Viuda-Martos, M., López-Marcos, M.C., Fernández-López, J., Sendra, E., López-Vargas, J.H. and Pérez-Álvarez, J.A. (2010), Role of Fiber in Cardiovascular Diseases: A Review. Comprehensive Reviews in Food Science and Food Safety, 9: 240-258.
Zhang, Y., Sun, Y., Xi, W., Shen, Y., Qiao, L., Zhong, L., ... Zhou, Z. (2014). Phenolic compositions and antioxidant capacities of Chinese wild mandarin (Citrus reticulata Blanco) fruits. Food Chemistry, 145, 674–680. https://doi.org/10.1016/j.foodchem.2013.08.012
Xi,W.P., Fang, B., Zhao, Q., Jiao, B.N., Zhou, Z.Q., (2014). Flavonoid composition and antioxidant activities of Chinese local pummelo (Citrus grandis Osbeck.) varieties. Food Chem, 161: 230–238.
Fang, B., Zhao, Q., Xi, W., Zhou, Z., Jiao, B., (2013). Determination of flavonoids in 10 pummelo and pummelo hybrid fruits by ultra performance liquid chromatography. Sci Agric Sinica, 46: 1892–1902. (in Chinese)
Montanari A, Chen J, Widmer W. (1998). Citrus flavonoids: a review of past biological activity against disease. In: Manthey JA, Buslig BS, editors. Flavonoids in the living system. New York: Plenum Press; p. 103–116.
Ho S, Kuo CT. (2014). Hesperidin, nobiletin, and tangeretin are collectively responsible for the anti-neuroinflammatory capacity of tangerine peel (Citri reticulatae pericarpium). Food Chem Toxicol. 71:176–182.
Musumeci L, Maugeri A, Cirmi S, Lombardo GE, Russo C, Gangemi S, Calapai G, Navarra M. (2020). Citrus fruits and their flavonoids in inflammatory bowel disease: an overview. Nat Prod Res. 34(1):122–136.
Long X, Zeng X, Yan H, Xu M, Zeng Q, Xu C, Xu Q, Liang Y, Zhang J. (2021). Flavonoids composition and antioxidant potential assessment of extracts from Gannanzao Navel Orange (Citrus sinensis Osbeck Cv. Gannanzao) peel. Nat Prod Res. 35(4):702–706.
Li S, Wang H, Guo L, Zhao H, Ho CT. (2014). Chemistry and bioactivity of nobiletin and its metabolites. J Funct Foods. 6:2–10.
Lin D, Xiao M, Zhao J, Li Z, Xing B, Li X, Kong M, Li L, Zhang Q, Liu Y, et al. (2016). An overview of plant phenolic compounds and their importance in human nutrition and management of type 2 diabetes. Molecules. 1(10):1374–1393.
Celano R, Campone L, Pagano I, Carabetta S, Di Sanzo R, Rastrelli L, Piccinelli AL, Russo M. (2019). Characterisation of nutraceutical compounds from different parts of particular species of Citrus sinensis ‘Ovale Calabrese’ by UHPLC-UV-ESI-HRMS. Nat Prod Res. 33(2):244–251.
Middleton E, Kandaswami C. (1994). Potential health-promoting properties of Citrus flavonoids. Food Technol. 48(11):115–119.
Samman S, Wall PML, Cook NC. (1996). Flavonoids and coronary heart disease: dietary perspectives. In: Manthey JA, Buslig BS, editors. Flavonoids in the living system. New York: Plenum Press; p. 469–481.
Faraneh Zareiyan & Habibollah Khajehsharifi (2022) Bioactive compounds analysis in ethanolic extracts of Citrus maxima and Citrus sinensis exocarp and mesocarp, Natural Product Research, 36:17, 4505-4508.
Joglekar, J.J.; Munde, Y.S.; Jadhav, A.L.; Bhutada, D.S.; Radhakrishnan, S.; Kulkarni, M.B. (2021). Mechanical and Morphological Properties of Citrus Maxima Waste Powder Filled Low-Density Polyethylene Composites. Mater. Today Proc. 47, 5640–5645.
N.F. Mat Zain, (2014). Preparation and characterization of cellulose and nanocellulose from pomelo (Citrus grandis) albedo, J. Nutr. Food Sci. 05 (01) 10-13.
J. Ortiz, G. Zhang, D.A. McAdams, (2018). A model for the design of a pomelo peel bioinspired foam, J. Mech. Des. Trans. ASME 140 (11) 1-5.
H.S. Owens, M.K. Veldhuis, W.D. Maclay, (1951). Making use of tons of citrus waste, Yearb. Agric. 268—274.
Czech, A., Zarycka, E., Yanovych, D., Zasadna, Z., Grzegorczyk, I., & Kłys, S. (2020). Mineral content of the pulp and peel of various citrus fruit cultivars. Biological Trace Element Research, 193(2), 555-563.
Sanjay Kumar, Pankaj Gautam, Dr. Avnish Chauhan (2021) Phytochemical, Pharmacological Properties And Bitterness Causing Compounds Of Pomelo (Citrus Maxima): A Mini Review. Elementary Education Online, 20 (2), 2666-2678. doi:10.17051/ilkonline.2021.02.283
Väisänen, O. Das, L. Tomppo, A review on new bio-based constituents for natural fiber-polymer composites, J. Cleaner Prod. 149 (2017) 582–596.
HPS.A. Khalil, M.A. Tehrani, Y. Davoudpour, A.H. Bhat, M. Jawaid, A. Hassan (2013). Natural fiber reinforced poly(vinyl chloride) composites: a review, J. Reinf. Plast. Compos. 32 (5) 330–356,
Joglekar, J.J.; Munde, Y.S.; Jadhav, A.L.; Bhutada, D.S.; Radhakrishnan, S.; Kulkarni, M.B. (2021). Studies on effective utilization of Citrus Maxima fibers based PVC composites. Mater. Today Proc. 42, 578—583, https://doi.org/10.1016/j.matpr.2020.10.648.
Olatunji O. (2015). Natural Polymers: Industry Techniques and Applications. Springer; 2015. doi: 10.1007/978-3-319-26414-1
Wei, Y., Fang, Z., Zheng, L., Tan, L., & Tsang, E. P. (2016). Green synthesis of Fe nanoparticles using citrus maxima peels aqueous extracts. Materials Letters, 185, 384–386.
Li, J., Hu, J., Xiao, L., Wang, Y., Wang, X., (2018). Interaction mechanisms between α-Fe2O3, γ-Fe2O3 and Fe3O4 nanoparticles and Citrus maxima seedlings. Sci. Total Environ. 625, 677–685.
J. Yu, D. Xu, H.N. Guan, C. Wang, L.K. Huang, (2016). Facile one-step green synthesis of gold nanoparticles using Citrus maxima aqueous extracts and its catalytic activity, Mater. Lett. 166:110–112.
Pavithra, N.S., Lingaraju, K., Raghu, G.K., Nagaraju, G., (2017). Citrus maxima (Pomelo) juice mediated eco-friendly synthesis of ZnO nanoparticles: applications to photocatalytic, electrochemical sensor and antibacterial activities. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 185, 11–19.
Aydoğmuş, E., Arslanoğlu, H., Dağ, M., Production of waste polyethylene terephthalate reinforced biocomposite with RSM design and evaluation of thermophysical properties by ANN. Journal of Building Engineering, 2021: 44, 103337.
Şahal, H., Aydoğmuş, E., Production and characterization of palm oil based epoxy biocomposite by RSM design. Hittite Journal of Science and Engineering, 2021: 8(4), 287-297.
Dağ, M., Aydoğmuş, E., Yalçin, Z. G., Arslanoğlu, H., Diatomite reinforced modified safflower oil-based epoxy biocomposite production: Optimization with RSM and assessment of outcomes by ANN. Materials Today Communications, 2023: 35, 106327.
Aydoğmuş, E., Dağ, M., Yalçın, Z. G., & Arslanoğlu, H. (2022). Synthesis and characterization of EPS reinforced modified castor oil-based epoxy biocomposite. Journal of Building Engineering, 47, 103897.
Şahal, H., & Aydoğmuş, E. (2021). Production and characterization of palm oil based epoxy biocomposite by RSM design. Hittite Journal of Science and Engineering, 8(4), 287-297.
Dağ, M., Yanen, C., & Aydoğmuş, E. (2022). Effect of boron factory components on thermophysical properties of epoxy composite. European Journal of Science and Technology, 36, 151-154.
Buran, A., Durğun, M. E., & Aydoğmuş, E. (2022). Cornus alba Reinforced Polyester-Epoxy Hybrid Composite Production and Characterization. Avrupa Bilim ve Teknoloji Dergisi, (43), 116-120.
Buran, A., Durğun, M. E., Aydoğmuş, E., & Arslanoğlu, H. (2023). Determination of thermophysical properties of Ficus elastica leaves reinforced epoxy composite. Firat University Journal of Experimental and Computational Engineering, 2(1), 12-22.
Demirel, M. H., & Aydoğmuş, E. (2022). Waste polyurethane reinforced polyester composite, production, and characterization. Journal of the Turkish Chemical Society Section A: Chemistry, 9(2), 443-452.
Orhan, R., Aydoğmuş, E., Topuz, S., & Arslanoğlu, H. (2021). Investigation of thermo-mechanical characteristics of borax reinforced polyester composites. Journal of Building Engineering, 42, 103051.
Aydoğmuş, E., & Arslanoğlu, H. (2021). Kinetics of thermal decomposition of the polyester nanocomposites. Petroleum Science and Technology, 39(13-14), 484-500.
Gencel, O., Aydoğmuş, E., Güler, O., Ustaoğlu, A., Sarı, A., Hekimoğlu, G., ... & Ozbakkaloglu, T. (2024). Sustainable polyurethane biocomposite foams by improved microstructure, acoustic characteristics, thermoregulation performance and reduced CO2 emission through phase change material integration. Journal of Energy Storage, 103, 114372.
Gencel, O., Aydoğmuş, E., Güler, O., Ustaoğlu, A., Sarı, A., Hekimoğlu, G., ... & Maraşlı, M. (2024). Biocomposite foams consisting of microencapsulated phase change materials for enhanced climatic regulation with reduced carbon dioxide emissions in buildings. Construction and Building Materials, 448, 138214.
Aydoğmuş, E. (2022). Biohybrid nanocomposite production and characterization by RSM investigation of thermal decomposition kinetics with ANN. Biomass Conversion and Biorefinery, 12(10), 4799-4816.
Yılmaz, E., Aydoğmuş, E., & Demir, A. (2022). Life cycle assessment and characterization of tincal ore reinforced polyester and vinylester composites. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 5(2), 183-194.
Dağ, M., Aydoğmuş, E., Arslanoğlu, H., & Yalçin, Z. G. (2024). Exploring role of polyester composites in biocomposites for advanced material technologies: a comprehensive review. Polymer-Plastics Technology and Materials, 1-25.
Musa, C., Zaidi, M., Depriester, M., Allouche, Y., Naouar, N., Bourmaud, A., ... & Delattre, F. (2024). Development of foam composites from flax gum-filled epoxy resin. Journal of Composites Science, 8(7), 244.
Deniz, Ş., Aydoğmuş, E., Kar, F., & Arslanoğlu, H. (2024). Manufacturing and characterization of waste polyethylene terephthalate-based functional composites reinforced with organic and inorganic fillers. Polymer-Plastics Technology and Materials, 1-16.
