Application of mathematical models for predicting the trihalomethanes content in drinking water in the city of Kumanova, North Macedonia
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DOI:
https://doi.org/10.59287/ijanser.715Keywords:
Thms, Physico-Chemical Parameters, Drinking Water, Mathematical Models for Prediction, HealthAbstract
Trihalomethanes (THMs) are created as a result of the reaction between chlorine used to disinfect drinking water and natural organic matter in water. At high levels, THMs have been associated with cancer. As a consequence, THMs must be constantly monitored. They are mainly determined by the method of gas chromatography, which is a more difficult procedure and at a higher cost. In recent years, however, mathematical models have been used to predict THMs. These models work by measuring some physico-chemical parameters of drinking water, those values of these parameters are replaced in mathematical models and the THMs content in drinking water can be predicted. The main purpose of this paper was to predict the content of THMs in the drinking water of the city of Kumanova. The measured parameters were: temperature, residual chlorine, pH, electrical conductivity, chemical oxygen, total dissolved solids and chlorides. Measurements were made during the spring season 2022 in the four sampling points. Ten mathematical models were used for prediction and of them the average value with standard deviation of THM was 26.9532 ± 10.03 μg/L. From the result we can conclude that content of THM does not pose a risk to the health of the population.
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References
Bujar H. Durmishi (2013). Study of the variation of the content of trihalomethanes (THMs) in the drinking water of the city of Tetova with advanced analytical methods, PhD, University of Tirana, Tirana, R. of Albania, 100-131.
Krasner, S. W., McGuire, M. J., Jacangelo, J. G., Patania, N. L., Reagan, K. M., and Aieta, M. E. (1989). The Occurrence of Disinfection By-products in US Drinking Water. Journal of American Water Works Association, 81, (8), 41-53.
Graves, C. G., Matanoski, G. M., Tardiff, R. G. (2002 ). Weight of evidence for an association between adverse reproductive and developmental effects and exposures to disinfection by-products: A critical review. Regul Toxicol Pharmacol, 34, 103 –124.
Rook, J. J. (1974). Formation of haloforms during chlorination of natural water. Water Treat. Exam. 23, 234-240.
Golfinopoulos, Spyros K, Nikos K. Xilourgidis, Maria N. Kostopoulou, and Themistokles D. Lekkas. (1998). Use of a multiple regression model for predicting trihalomethane formation. Water Resources, 32, Number 9, 2821-2829[6] Rodriguez, M. J., and Serodes, J. B. (2001). Spatial and temporal evolution of trihalomethanes in three water distribution systems. Water Research, 35, (6), 1572 –1586.
Villanueva C. M., Cantor K. P., Grimalt J. O., Castaño-Vinyals G., Malats N., Silverman D. (2006). Assessment of lifetime exposure to trihalomethanes through different routes. Occup Environ Med, 63, 273–7.
Elshorbagy, W. (2000). “Kinetics of THM Species in Finished Water”. J. Water Resour. Plng. and Mgmt., ASCE, 126 (1), 21-28.
Clark, R. M., and Sivaganesan Mano. (1998).Predicting Chlorine Residuals and Formation of TTHMs in Drinking Water. J. Environ. Engrg., 124 (12), 1203-1210.
Montgomery, W. (1993). Mathematical modelling of the formation of THMs and HAAs in chlorinated natural waters. Denver, Colorado, AWW.
Clark, R. M., Pourmoghaddas, H., Wymer, L., and Dressmand R. (1996). Modeling the Kinetics of Chlorination By-products Formation: The Effects of bromide. J. SRT-aqua, 45(3), 112-119.
Karimi, A., and Singer, P. (1991). Trihalomethane Formation in Open Reservoirs. J. AWWA, 83(3), 84-88.
Canale, R., Chapara, C., Amy, G., and Edwards, M. (1997). Trihalomethane Precursor Model for Lake Youngs. Washington Journal of Environmental Engineering, ASCE, 123 (5), 259-265.
Government of the Republic of Macedonia. (2004). State Drinking Water Regulation, Official Gazette No. 57/2004. Skopje: Government of the Republic of Macedonia.
Dwivedi Padmanabh and Sonar Santoshi (2004). Evaluation of physical-chemical and biological parameters in water reservoir around hills, Doimukh (dist. Papum pare) Arunanchal Pradesh. Poll. Res. 23(1), 101-104.
Ali Akbar Babaei, Leila Atari, Mehdi Ahmadi, Kambiz Ahmadiangali, Mirzaman Zamanzadeh and Nadali Alavi (2015). Trihalomethanes formation in Iranian water supply systems:predicting and modeling. Journal of Water and Health, 13(3), 859 – 869.